Octyl (2E)-2-[2-(di­phenyl­phosphan­yl)benzyl­idene]hydrazinecarbodi­thio­ate

Authors

Izuddin Asri, University of Brunei Darussalam
Malai Haniti S. A. Hamid, University of Brunei DarussalamFollow
Aminul Huq Mirza, University of Brunei DarussalamFollow
Mohammad Akbar Ali, University of Brunei Darussalam
Mohammad Rezaul Karim, Tennessee State UniversityFollow

Document Type

Article

Publication Date

6-1-2014

Abstract

The title compound, C28H33N2S2P, adopts the thione tautomeric form, as supported by the C—S distance [1.6744 (18) Å]. The Schiff base exhibits an E conformation about the C=N bond but a Z conformation about the C—N bond. The terminal chain is disordered over two sets of sites with an occupancy ratio of 0.732 (3):0.268 (3). In the crystal, pairs of N—N—H hydrogen bonds between the thione groups link neighbouring mol­ecules into centrosymmetric dimers.

Recommended Citation

I. Asri, M.H.S.A. Hamid, A.H. Mirza, Mohammad Akbar Ali, Mohammad Rezaul Karimb "Octyl (2E)-2-[2-(di­phenyl­phosphan­yl)benzyl­idene]hydrazinecarbodi­thio­ate" Acta Crystallogr Sect E Struct Rep Online. 2014 Jun 1; 70(Pt 6): o633–o634. https://dx.doi.org/10.1107%2FS1600536814008459