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We obtained high-resolution spectroscopic observations of 34 γ Doradus candidates. From the red-wavelength spectra, we determined spectral classes, radial velocities, and projected rotational velocities. The spectra of seven late A or early F stars show metallic lines that have composite profiles consisting of a narrow component near the center of a broad line, indicating that they may be shell stars or binaries. Several stars, including HD 152896, HD 173977, HD 175337, and HD 195068/9, show large line profile asymmetries. Two stars, HD 11443 (=α Trianguli) and HD 149420, are ellipsoidal variables and not γ Doradus stars. The percentage of binary systems in our sample may be as high as 74%.